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Report No. NB2022076007EN Date:

Applicant Name : NANJING

Applicant Address : 388# GANJIAXIANG

Product Name : Refrigerant

Received Date : July 12,

Compilation Period : July 12,

Regulatory Requirements :

As requested

according

Labelling of Chemicals (GHS) Rev_8

Signed for and on behalf of Guangdong NewBest

Approved by:

Manager

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Date: July 14, 2022

NANJING REFINERY CO., LTD

GANJIAXIANG STREET, QIXIA DISTRICT, NANJING

Refrigerant R290 (high purity propane)

12, 2022

12, 2022 to July 14, 2022

requested by the applicant, the Safety Data Sheet is prepared

according to Globally Harmonized System of Classification and

Labelling of Chemicals (GHS) Rev_8（2019）.

NewBest Testing Service Co., Ltd.

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Page: 1/9

NANJING

prepared

to Globally Harmonized System of Classification and

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: Refrigerant

: R290

: /

: NANJING

: 388#

: 025

: /

: /

: 025

1.1 Product Identification

1.2 Model No.

1.3 Recommended Use

1.4 Manufacturer Name

1.5 Manufacturer Address

1.6 Manufacturer Tel

1.7 Manufacturer Fax

1.8 Manufacturer Email

1.9 Emergency Phone

SECTION 1. Identification of the substance/preparation

2.3 Signal word:

Danger

2.4 Hazard description:

H220 Extremely flammable gas.

H280 Contains gas under pressure; may

2.5 Precautionary description:

P210 Keep away from heat, hot surfaces, sparks, open

2.1 Hazard Class:

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Rev_8

(part 2~4), classification of risk categories.

Flammable gas, category 1

High pressure gas, compressed gas

2.2 Pictograms:

SECTION 2. Hazards identifications

Report No. NB2022076007EN Date:

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Refrigerant R290 (high purity propane)

R290

NANJING REFINERY CO., LTD

388# GANJIAXIANG STREET, QIXIA DISTRICT, NANJING

025-58989858

025-85477110

substance/preparation and company

under pressure; may explode if heated.

surfaces, sparks, open flames and other ignition sources.

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Rev_8

(part 2~4), classification of risk categories.

Date: July 14, 2022

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NANJING

No smoking.

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Rev_8

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Ingredient(s) of the product: Pure

SECTION 3. Composition / information

General advice: Immediate medical attention

doctor in attendance.

4.1 Following inhalation:

If feeling uncomfortable, victim should

4.2 Following skin contact:

Take off contaminated clothing and shoes immediately.

minutes and consult a physician if feeling uncomfortable.

4.3 Following eye contact:

In case of contact may cause irritation, immediately flush eyes with

minutes. Call a physician immediately if eyes are hurt.

4.4 Following ingestion:

If it is ingested, Seek medical attention.

SECTION 4. First aid measures

5.1 Hazardous Characteristics:

Flammable gas.

Will form explosive mixtures with air.

Containers exposed to fire may release the contents through pressure relief valves thereby increasing

fire intensity and/ or vapour concentration.

Vapours may travel to source of ignition

5.2 Extinguishing Media:

Dry powder, Chemical foam, Carbon dioxide,

SECTION 5. Firefighting measures

Report No. NB2022076007EN Date:

Substance name

Propane

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information on ingredients

attention is required. Show this safety data sheet (SDS)

be moved into fresh air. Seek medical attention.

Take off contaminated clothing and shoes immediately. Wash off with plenty of water for at least 15

minutes and consult a physician if feeling uncomfortable.

In case of contact may cause irritation, immediately flush eyes with plenty of water for at least 15

immediately if eyes are hurt.

Containers exposed to fire may release the contents through pressure relief valves thereby increasing

fire intensity and/ or vapour concentration.

ignition and flash back.

dioxide, water mist.

Date: July 14, 2022

Conc. (%) CAS. No

≥99.9 74-98-

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(SDS) to the

off with plenty of water for at least 15

plenty of water for at least 15

Containers exposed to fire may release the contents through pressure relief valves thereby increasing

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No

-6

SAFETY DATA

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5.3 Firefighting procedures:

As in any fire, wear self-contained breathing apparatus

protective gear.

Extinguish fire in a safe distance with enough

5.4 Hazardous combustion products:

Carbon monoxide

6.1 Personal precautions, protective equipment

Wear appropriate protective measures

Beware of vapours accumulating to form

Ensure adequate ventilation.

Remove all sources of ignition.

Evacuate personnel to safe areas. Keep

6.2 Environmental precautions:

Discharge into the environment must be

6.3 Cleaning method:

Strengthen ventilated.

SECTION 6. Accidental release measures

7.1 Handling Notes:

Keep indoor ventilation or local exhaust

Stay away from heat and direct sunlight.

Keep away from heat, hot surfaces, sparks,

7.2 Storage Notes:

Stored in cool and dry condition

Store in a well-ventilated place.

Do not store with incompatible material

SECTION 7. Safe handling and storage

Report No. NB2022076007EN Date:

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contained breathing apparatus(MSHA/NIOSH approved or equivalent)and full

enough protection

equipment and emergency procedures:

Wear appropriate protective measures (SEE SECTION 8).

form explosive concentrations.

Keep people away from upwind of spill/leak.

be avoided.

measures

exhaust device.

Stay away from heat and direct sunlight.

sparks, open flames and other ignition sources. No smoking.

material (see section 10.2)

Date: July 14, 2022

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equivalent)and full

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SAFETY DATA

Report No. NB2022076007E Date:

N

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8.1 Occupational Exposure Limit:

8.2 Engineering Control:

Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local

exhaust ventilation and good general extraction. If these are

particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.

Ensure that eyewash stations and safety showers are proximal to the

8.3 Personal Protection:

8.4 Sanitary Measure:

Forbid smoking, eating and drinking in

SECTION 8. Exposure controls / personal

Substance Country/Region

Propane Germany(AGS)

General requirement:

Respiratory:

If exposure

experienced, use a full

(US) or type AXBEK (EN 14387)

Eyes： Wear protective

Hands： Wear antifreeze

SECTION 9. Physical and chemical properties

Appearance and Color

Odour

PH value

DATA SHEET FOR CHEMICAL PRODUCTS

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Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local

general extraction. If these are not sufficient to maintain concentrations

particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.

eyewash stations and safety showers are proximal to the work-station location.

in working places. Washing hands after handling products.

personal protection

Occupational exposure

limit (8h)

Occupational exposure

limit (short

ppm mg/m³ ppm

1000 1800 4000

limits are exceeded or if irritation or other symptoms

experienced, use a full-face respirator with multi-purpose combination

(US) or type AXBEK (EN 14387) respirator cartridges.

protective goggle (Conform to EC EN 166 or US-NIOSH).

antifreeze gloves.

properties

Colorless gas

Odorless

No Data

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Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local

not sufficient to maintain concentrations of

particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.

location.

products.

exposure

time)

mg/m³

7200

symptoms are

purpose combination

NIOSH).

SAFETY DATA

Report No. NB2022076007E Date:

N

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10.1 Stability:

Stable under recommended storage and

10.2 Material for avoiding:

Strong oxide, acid, alkali, naked light.

10.3 Contact conditions for avoiding:

Sunlight, high temperature.

10.4 Hazardous decomposition products:

Under normal conditions of storage and

SECTION 10. Stability and reactivity

Flammability

Density

Relative steam density (air = 1)

Vapor pressure(MPa)

Octanol/water partition coefficient

Viscosity

Flash point(℃,Closed cup)

Boiling point(℃)

Melting point (℃)

Evaporation rate (kg/s)

UEL %(V/V)

LEL %(V/V)

Auto-ignition temperature(℃)

Decomposition temperature(℃)

Solubility

DATA SHEET FOR CHEMICAL PRODUCTS

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and handling conditions (See section 7).

light.

products:

and use, hazardous decomposition products should not

Combustible

0.58（-44.5℃）

1.6

840(20℃)

2.36

Not Applicable

-104

-42.1

-189.7

No Data

9.5

2.1

450

No Data

Slightly soluble in water, soluble in ethanol, ether,

chloroform

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not be produced.

ether,

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11.1 Acute toxicity:

Based on available data, the classification

11.2 Skin corrosion/irritation:

Based on available data, the classification

11.3 Serious eye damage/irritation:

Based on available data, the classification

11.4 Respiratory or skin sensitisation:

Based on available data, the classification

11.5 Germ cell mutagenicity:

Based on available data, the classification

11.6 Carcinogenicity:

Based on available data, the classification

11.7 Reproductive toxicity:

Based on available data, the classification

11.8 STOT-single exposure:

Based on available data, the classification

11.9 STOT-repeated exposure:

Based on available data, the classification

11.10 Aspiration hazard.:

Based on available data, the classification

SECTION 11. Toxicological information

12.1 Toxicity:

No data available.

12.2 Persistence and degradability:

No data available.

12.3 Bioaccumulative potential:

SECTION 12. Ecological information

Report No. NB2022076007EN Date:

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classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

classification criteria are not met.

information

Date: July 14, 2022

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Transportation Precautions: Shipment of

retardant devices, prohibit using mechanical

prohibited shipping or transportation with oxidants,

board, and with a triangular wooden pad cards

SECTION 14. Transport information

No data available.

12.4 Mobility in soil

No data available.

12.5 Other Dangers:

No data available.

13.1 Handling method for waste:

Handling waste according to the local

companies recommended by local laws.

13.2 Handling method for uncleaned packaging

Containers may still present chemical hazard

fire. Return to supplier for recycling if possible.

SECTION 13. Disposal considerations

Report No. NB2022076007EN Date:

Packaging Label

UN NO 1978

Technical name Propane

Transport hazard class 2.1

Subsidiary hazard class None

Packing group Not Applicable

Marine pollutant No

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of the goods vehicle exhaust pipe must be equipped

mechanical equipment and toolsof which easy to produce sparks.

oxidants, halogens etc. Height shall not exceed the vehicle

cards firmly to prevent rolling. Cylinders generally flat,

regulations. Contact specific waste disposal company

packaging

chemical hazard when empty. Keep away from hot and ignition

fire. Return to supplier for recycling if possible.

Date: July 14, 2022

Propane

Applicable

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with fire

sparks. Strictly

vehicle fence

flat, and the

company or

ignition source of

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bottles should be in the same direction, should not cross. A safety helmet must be fitted for cylinder

transport. Transport vehicles should be equipped

and emergency equipment leakage during transport.

whether container integrity, sealing. The transport unit must be placarded and marked in accordance with

relevant transporting

15.1 Safety, health and environmental regulations / laws for pure substances or

Catalogue of hazardous chemicals (2015 Edition)

Catalog number of hazardous chemicals:

CAS No.: 74-98-6

English name: propane

15.2 Safety assessment of chemical substances

Not evaluated

SECTION 15. Regulatory information

The above information is based on the

the date hereof. Since this information may be

may be unfamiliar and since data made available

of the information, we do not assume any responsibility for the result of its use, this information is furnished

upon condition that the person receiving it shall

for his particular purpose.

SECTION 16. Other information

Report No. NB2022076007EN Date:

***************

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should be in the same direction, should not cross. A safety helmet must be fitted for cylinder

equipped with the appropriate variety and quantity of fire

and emergency equipment leakage during transport. Before transport, should be preceded by checking

whether container integrity, sealing. The transport unit must be placarded and marked in accordance with

Safety, health and environmental regulations / laws for pure substances or mixtures

Catalogue of hazardous chemicals (2015 Edition)

chemicals: 139

substances

the data of which we are aware and is believed to be

may be applied under conditions beyond our control and

available subsequent to the date hereof may suggest

of the information, we do not assume any responsibility for the result of its use, this information is furnished

shall make his own determination of the suitability of

Date: July 14, 2022

*************** END ***************

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should be in the same direction, should not cross. A safety helmet must be fitted for cylinder

fire equipment

Before transport, should be preceded by checking

whether container integrity, sealing. The transport unit must be placarded and marked in accordance with

mixtures

be correct as of

and with which

modifications

of the information, we do not assume any responsibility for the result of its use, this information is furnished

of the material

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