ReportNo.:TSZ24ML040A01-01Page1/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108材料安全数据表MaterialSafetyDataSheet签发时间Dateofissue:2024.12.30WrittenbyApprovedby深圳天溯计量检测股份有限公司ShenzhenTiansuCalibrationandTestingCo.,Ltd.本报告本年度有效有效期至2025年12月31日样品名称:Samplename:锂离子电池组Lithium-ionbatterypack样品型号:Samplemodel:TCMT-155委托单位:Applicant:永康市易事尔工贸有限公司YongkangYishierIndustryandTradeCo.,Ltd
ReportNo.:TSZ24ML040A01-01Page2/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108*TheMSDSispreparedbasedontheinformationprovidedbyclient.ThecontentsandformatsofthisMSDSarerevisedasperclient'srequest.这份材料安全数据表是根据客户提供的信息编辑,其内容和格式按客户要求来修订。第一部分化学品及企业标识Section1-ChemicalProductandCompanyIdentification产品名称ProductName锂离子电池组Lithium-ionbatterypack型号ModelTCMT-155商标TradeMark/额定参数Ratings18.5V/4500mAh/83.25Wh重量Weight798.070g生产单位Manufacturer永康市易事尔工贸有限公司YongkangYishierIndustryandTradeCo.,Ltd生产单位地址ManufacturerAddress浙江省金华市永康市芝英镇游仙塘村黄龙路23号501室Room501,No.23HuanglongRoad,YouxiantangVillage,ZhiyingTown,YongkangCity,JinhuaCity,ZhejiangProvince应急电话EmergencyTelephone18357969892传真Fax--第二部分成分信息Section2-CompositionInformation化学成分ChemicalComposition化学式ChemicalFormulaCAS号CASNo.重量含量(%)Weight(%)钴酸锂LithiumcobaltateLiCoO212190-79-315-40石墨GraphiteC7782-42-510-30六氟磷酸锂LithiumhexafluorophosphateLPF621324-40-310-30铜箔CopperCu7440-50-87-13
ReportNo.:TSZ24ML040A01-01Page3/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108铝箔AuminiumAl7429-90-55-10镍NickeNi7440-02-01-5第三部分-危险性概述Section3-HazardsIdentification紧急情况概述Emergencyoverview不适用N/A标签元素Labelelements:危险标签图Hazardpictogram(s)不适用NotApplicable提示语Signalword不适用NotApplicable危险声明Hazardstatement(s)不适用NotApplicable预防声明Precautionarystatement(s):预防Prevention不适用NotApplicable反应Response不适用NotApplicable废弃处理Disposal不适用NotApplicable环境危害Environmentalhazards:无相关信息Norelevantinformation重要症状Importantsymptoms:见第11部分更多信息Seesection11formoreinformaton第四部分-急救措施Section4-FirstAidMeasures眼睛接触Eyecontact万一接触,立即用大量的清水冲洗至少15分钟,翻起上下眼睑,直到化学的残留物消失为止,迅速就医。Flusheyeswithplentyofwaterforleast15minutes,occasionallyliftingtheupperandlowereyelids.Getmedicalaid.皮肤接触Skincontact万一接触,用大量的水冲洗至少15分钟,同时除去污染的衣物和鞋子,迅速就医。Removecontaminatedclothesandrinseskinwithplentyofwaterorshowerfor15minutes.Getmedicalaid.吸入Inhalation立即从暴露处移至空气清新处,如果呼吸困难给予输氧,立即就医。Removefromexposureandmovetofreshairimmediately.Useoxygenifavailable.摄入Ingestion饮用两杯牛奶或水,如果当事人仍然清醒可以采取催吐的方法,并且立即就医。Giveateast2glassesofmilkorwater.Inducevomitingunlesspatientsunconscious.Callaphysician.
ReportNo.:TSZ24ML040A01-01Page4/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108第五部分消防措施Section5-FireFightingMeasures燃点FlashPoint不适用N/A自燃温度AutolgnitionTemperature不适用N/A灭火介质ExtinguishingMedia碳氢表面活性剂,二氧化碳Hydrocarbonsurfactant,CO2特殊灭火程序SpecialFire-FightingProcedures自给式呼吸器Self-containedbreathingapparatus异常火灾或爆炸UnusualFireandExplosionHazards当电芯暴露于过热的环境中时,安全阀可能会打开Celmayventwhensubjectedtoexcessiveheatexposngbatterycontents燃烧产生的危险物品HazardousCombustionProducts一氧化碳,二氧化碳,锂氧化物烟气Carbonmonoxide,carbondioxide,lithiumoxidefumes.第六部分泄露应急处理Section6-AccidentalReleaseMeasures个人预防措施、保护设备和应急程序:如果电池被泄露,让人员离开该区域直到烟雾消散。提供最大限度的通风,清除有害气体。首选的反应就是离开这个地区并消散气体,避免皮肤和眼睛接触或吸入气体。用吸收剂清除溢出的液体然后焚烧。如果电池泄漏发生时,液体可以用砂、泥土或其他惰性物质来吸收,污染区域应该保持通风。Personalprecautions,protectiveequipmentandemergencyprocedures:Ifthebatteryisreleased,removepersonnelfromareauntifumesdissipate.Providemaxmumventlationtoclearouthazardousgases.Thepreferredresponseistoeavetheareaandallowthevaporstodssipate,Avoidskinandeyescontactorinhalationofvapors.Removespilledliquidwithabsorbentandincinerated.fleakageofthebatteryhappens,liquidcouldbeabsorbedbyusingsand,earthorotherinertsubstanceandcontaminatedareashouldbeventilatedmeantime.环境预防措施:不允许产品到达排水系统或任何水源。如果渗透进排水系统或任何水源,通知相应的部门。不允许进入下水道/表面或地下水。Environmentprecautions:Donotallowproducttoreachsewagesystemoranywatersource.Informrespectiveauthoritiesincaseofseepageintowatercourseorsewagesystem.Donotallowtoentersewers/surfaceorgroundwater.抑制和清理材料的方法:如果电池外壳被拆除,少量电解液可能会泄漏。收集所有材料放进一个塑料容器。根据当地的法律法规来处置,避免可溶物质进入大地、下水道或水源。Methodsandmaterialforcontainmentandcleaningup:Ifbatterycasingisdismantled,smallamountsofelectrolytemayleak.Collectallreleasedmaterialinaplastc
ReportNo.:TSZ24ML040A01-01Page5/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108linedcontainer.Disposeoffaccordngtothelocallawandrules,Avoidleachedsubstancestogetintotheearth,canalzationorwaters.第七部分操作处置和储存Section7-HandlingandStorage操作处置Handling禁止打开、毁坏或焚烧电池,因为电池有可能在这些处理过程中发生爆炸、破裂或泄露等事故。禁止将电池短路、过充、强制放电或扔入火中。禁止挤压或刺穿电池,或将电池浸入溶液中。Thebatteryshouldnotbeopened,destroyedorincinerate,sincetheymayeakorruptureandreleasetotheenvironmenttheingredientsthattheycontaininthehermetcallysealedcontaner.Donotshortcircutterminals,oroverchargethebattery,forcedover-dscharge,throwtofire.Donotcrushorpuncturethebattery,orimmerseinliquids.储存Storage禁止物理或电滥用,禁止高温储存,最好将电池储存在阴凉、干燥、通风及温度变化较小的环境中。禁止将电池接触加热设备,或将电池长时间直接暴露在阳光中。Avoidmechanicalorelectricalabuse.Storagepreferablyincool,dryandventilatedarea,whichissubjecttolittletemperaturechange.Storageathightemperaturesshouldbeavoided.Donotplacethebatterynearheatingequipment,norexposetodirectsunightforongperiods.其他要注意的防范措施OtherPrecautions拆解、挤压、直接放入火中或高温条件下,电池可能发生爆炸和燃烧。禁止短接或将电池正负极错误的安装在设备中。Thebatterymayexplodeorcauseburns,ifdisassembed,crushedorexposedtofireorhightemperatures.Donotshortorinstallwithincorrectpoarity.第八部分-接触控制和个体防护Section8-ExposureControls/PersonalProtection设计控制EngineeringControls设计局部排气通风或其它设计来控制粉尘、雾、烟雾和气体。Uselocalexhaustventlationorotherengineeringcontrolstocontrosourcesofdust,mist,fumesandvapor.Keepawayfromheatandopenflame.Storeinacool,dryplace.
ReportNo.:TSZ24ML040A01-01Page6/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108个人防护装备PersonalProtectiveEquipment呼吸防护:在正常情况下不需要。皮肤和身体防护:在正常情况下不需要,如果处理一个裂开的或泄漏的电池需要穿戴适当的防护服和手套。手保护:如果处理一个裂开的或泄漏的电池需要戴适当手套。眼睛保护:在正常情况下不需要,如果处理一个裂开的或泄漏的电池需要戴上安全眼镜。RespiratoryProtection:Notnecessaryundernormalcondtons.SkinandbodyProtection:Notnecessaryundernormalconditions,Wearsuitableprotectiveclothingandglovesifhandlinganopenorleakingbattery.Handprotection:Wearsuitableglovesifhandlinganopenorleakingbattery.EyeProtection:Notnecessaryundernormalcondtions,Wearsafetyglassesifhandinganopenorleakingbattery.其它防护装备OtherProtectiveEquipment在工作区域应该有一个立即可以使用的安全淋浴和喷水洗眼器。Haveasafetyshowerandeyewashfountainreadilyavailableinthemmedateworkarea.卫生措施HygieneMeasures在工作区域不得进食,饮水或吸烟。Donoteat,drink,orsmokenworkarea.Maintaingoodhousekeeping.第九部分物理和化学特性Section9-PhysicalandChemicalProperties颜色Color黑色Black气味Odour不适用NotApplicable酸碱度pH不适用NotApplicable熔点/凝固点Meltingpoint/freezingpoint不适用NotApplicable沸点、沸点范围:BoilingPointandBoilingrange不适用NotApplicable易燃度FlashPoint不适用NotApplicable自燃或爆炸的上、下极限Upper/lowerflammabilityorexplosivelimits不适用NotApplicable蒸汽压VaporPressure不适用NotApplicable
ReportNo.:TSZ24ML040A01-01Page7/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108蒸汽密度VaporDensity不适用NotApplicable相对密度Relativedensity不适用NotApplicable水溶性SolubilityinWater不适用NotApplicable自燃温度Auto-ignitiontemperature不适用NotApplicable分解温度Decompositiontemperature不适用NotApplicable蒸发速率Evaporationrate不适用NotApplicable易燃性(土壤、天然气)Flammability(soil,gas)不适用NotApplicable粘性Viscosity不适用NotApplicable第十部分稳定性和反应活性Section10-Stabilityandreactivity稳定性Stability产品在第七部分所述的条件下稳定TheproductisstableunderconditionsdescribedSection7应避免的条件ConditionstoAvoid加热70°C以上或焚烧、变形、毁坏、粉碎、拆卸、过充电、短路,长时间暴露在潮湿的条件下。Heatabove70°Corincinerate.Deform,Mutilate,Crush,Disassemble,Overcharge,Shortcircuit,Exposeoveralongperodtohumidconditions.不兼容的材料IncompatibleMaterials氧化剂,酸,碱。Oxidizingagents,acid,base.危险分解物HazardousDecompositionProducts一氧化碳、二氧化碳、氧化锂烟雾。Carbonmonoxide,carbondioxide,lithiumoxidefumes.危险反应的可能性PossibilityofHazardousReaction不适用NotApplicable第十一部分-毒理学资料Section11–ToxicologicalInformation刺激如果电芯的外壳受到机械、热或电的滥用到达一定程度,会发生刺激的风险。
ReportNo.:TSZ24ML040A01-01Page8/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108Irritation如果发生这种情况,可能会刺激皮肤、眼睛和呼吸道。Riskofirritationoccursonlyifthecellsmechanically,thermallyorelectricallyabusedtothepointofcompromsingtheenclosure.Ifthisoccurs,rritationtotheskin,eyesandrespiratorytractmayoccur.致过敏Sensitization不适用NotApplicable影响神经系统NeurologicalEffects不适用NotApplicable致畸Teratogenicity不适用NotApplicable再生毒性ReproductiveToxicity不适用NotApplicable诱变(遗传效应)Mutagenicity(GeneticEffects)不适用NotApplicable附带材料毒理性ToxicologicallySynergisticMaterials不适用NotApplicable第十二部分-生态学资料Section12-EcologicalInformation生态毒性EcologicalToxicity不适用NotApplicable在土壤中的流动性Mobilityinsoil不适用NotApplicable持久性和分解性PersistenceandDegradability不适用NotApplicable生物聚积Bioaccumulationpotential不适用NotApplicable其他不利影响OtherAdverseEffects不适用NotApplicable第十三部分-废弃处置
ReportNo.:TSZ24ML040A01-01Page9/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108Section13-DisposalConsiderations产品废弃处理建议Productdisposalrecommendation遵守当地、州和联邦法律和法规。Observelocal,stateandfederalawsandregulations.包装处理建议Packagingdisposalrecommendation废弃处理必须根据当地法规Disposalmustbemadeaccordingtooffcialregulations第十四部分运输信息Section14–TransportInformation运输标签Labelforconveyance锂电池标签LithiumBatteryLabelUN编号UNNumberUN3480或UN3481UN3480orUN3481运输风险类别Transporthazardclass(es)9包装等级Packinggroup--海洋污染物Marinepollutant无污染No联合国运输专用名称UNPropershippingname锂离子电池(包括锂离子聚合物电池)LithiumionBatteries(Incudinglithiumionpolymerbatteres)锂离子电池和设备包装在一起(包括锂离子聚合物电池)LithiumionBatteriespackedwithequipment(Includinglithumionpolymerbatteries)设备里内含锂离子电池(包括锂离子聚合物电池)LithiumionBatteriescontainedinequipments(Includinglithiumionpolymerbatteries)ICAO/IATA可根据国际民用航空组织(CAO),TI或国际航空协会(IATA)DGR66版本包装说明965第IB节规定或966~967第II节规定进行空运CanbeshippedbyairinaccordancewithinternatonalCivilAviationOrganizaton(ICAO),TIorInternationaAirTransportAssociation(IATA)DGR66thPackngInstructionsSectionIBof965orSectonIIof966~967appropriately.
ReportNo.:TSZ24ML040A01-01Page10/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108IMDGCODE《国际海运危险货物规则》特殊规定188IMDGCODE(Amdt42-24)InternationalMaritimeDangerousGoodsCodeunderSpecalProvision188IMDGCODE(Amdt42-24)ADR《国际危险货物道路运输欧洲协定》(ADR)根据特殊规定188EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsbyRoadunderSpecialProvision188RID《国际危险货物铁路运输欧洲协定》(RID)根据特殊规定188RegulatonsconcerningtheInternationalCarriageofDangerousGoodsbyRailunderSpecialProvision188危险品规例规定,运输前,每一个电池设计须通过联合国试验和标准手册38.3节所载的测试。ThedangerousgoodsregulationsrequrethateachbatterydesignbesubjecttotestscontainednSection38.3oftheUNManualofTestsandCriteriapriortobeingofferedfortransport.第十五部分法规信息Section15-Regulatoryinformation法律信息Lawinformation《危险物品规则》《DangerousGoodsRegulations》《对危险货物运输的有关规定的建议》《RecommendationontheTransportofDangerousGoodsModelRegulations》《国际海运危险货物规则》《InternatonalMaritimeDangerousGoods》《危险品安全运输技术指令》《TechnicalInstructionsfortheSafeTransportofDangerousGoods》《危险货物分类和品名编号》《ClassificationandcodeofdangerousGoods》《消费产品安全法》《ConsumerProductSafetyAct》(CPSA)《联邦环境污染控制法》《FederalEnvironmentalPolutionControlAct》(FEPCA)《资源保护及恢复法案》《ResourceConservationandRecoveryAct》(RCRA)《国际危险货物道路运输欧洲协定》《EuropeanAgreementconcerningtheInternationaCarriageofDangerous》《国际危险货物铁路运输欧洲协定》《ReguationsconcerningthenternationalCarriageofDangerous》根据所有联邦、州和地方法律。InaccordingwthalFederal,Stateandlocalaws.
ReportNo.:TSZ24ML040A01-01Page11/11PagesAddress:No.2JinlongAvenue,LonggangDistrct,Shenzhen,Guangdong,ChinaWeb:wwwtansu.orgEmaitsjc@tiansuorgTel:075589457984J3-2022-A01-0108第十六部分其它信息Section16-OtherInformation上面的信息被认为是准确代表了目前最好的信息提供给我们。然而,本文没有对商品性能保证或任何其他保证,包括明示或暗示,对这类信息的使用我们不承担责任。用户应作出自己的调查,以确定是否适合其特定用途的信息。虽然在此处所包含的数据的准备已经采取了合理的预防措施,这是仅为你提供的信息、考虑和调查。这个化学品安全技术说明书为本产品提供了安全操作指南和使用指南,它并不能对所有可能发生的情况提供建议,因此,您特殊使用该产品应先进行评估,以确定是否需要额外的预防措施。Theinformationaboveisbelievedtobeaccurateandrepresentsthebestinformationcurrentlyavailabletous.However,thisdocumentmakesnowarrantyofmerchantabilityoranyotherwarranty,expressorimplied,withrespecttosuchinformation,andweassumenoliabilityresultingfromitsuse.Usersshouldmaketheirowninvestigationstodeterminethesuitabilityoftheinformationfortheirparticularpurposes.Athoughreasonableprecautionshavebeentakeninthepreparationofthedatacontainedherein,itisofferedsoelyforyourinformaton,considerationandinvestigaton.Thismateriasafetydatasheetprovidesguidelinesforthesafehandlinganduseofthisproduct;itdoesnotandcannotadviseonallpossiblesituatons,therefore,yourspecificuseofthisproductshouldbeevaluatedtodetermineifadditionalprecautionsarerequired.--EndofReport----报告结束--